Oxygen-initiated stereoselective thermal isomerisation of a cyclobutane derivative in the solid state

• Main Authors: Chanthapally, Anjana, Yang, Hui, Quah, Hong Sheng, Webster, Richard D., Schreyer, Martin K., Wong, Ming Wah, Vittal, Jagadese J.
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2015
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Oxidation
• Online Access: https://hdl.handle.net/10356/107432; http://hdl.handle.net/10220/25623; http://dx.doi.org/10.1002/chem.201405228
• Institution: Nanyang Technological University

Solid-state [2+2] photochemical cycloaddition reactions have been extensively studied after the classical work of Schmidt in the 1960s. Of these, trans-1,2-bis(4′-pyridyl)ethylene (bpe) is one of the well-studied alkenes to synthesize tetrakis(4-pyridyl)cyclobutane (tpcb). However, almost all the so...