Platinum-catalysed ring-opening isomerisation of piperidine cyclopropanes

A range of cyclopropyl‐fused N‐tosyl piperidines have been synthesised and shown to undergo ring‐opening isomerisation on treatment with platinum(II) catalysts. The products can have either an endo‐cyclic or exo‐cyclic double bond. The selectivity is influenced by reaction temperature, solvent and,...

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Bibliographic Details
Main Authors: Barát, Viktor, Kasinathan, Sivarajan, Bates, Roderick Wayland
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2019
Subjects:
Online Access:https://hdl.handle.net/10356/90122
http://hdl.handle.net/10220/48397
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Institution: Nanyang Technological University
Language: English