Platinum-catalysed ring-opening isomerisation of piperidine cyclopropanes
A range of cyclopropyl‐fused N‐tosyl piperidines have been synthesised and shown to undergo ring‐opening isomerisation on treatment with platinum(II) catalysts. The products can have either an endo‐cyclic or exo‐cyclic double bond. The selectivity is influenced by reaction temperature, solvent and,...
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Main Authors: | Barát, Viktor, Kasinathan, Sivarajan, Bates, Roderick Wayland |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2019
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/90122 http://hdl.handle.net/10220/48397 |
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Institution: | Nanyang Technological University |
Language: | English |
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