[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides

• المؤلفون الرئيسيون: Gandamana, Dhika Aditya, Tamura, Sayako, Demirelli, Mesut, Kaga, Atsushi, Chiba, Shunsuke
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2017
• الموضوعات: Donor–acceptor cyclopropanes; Vinyl azides
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/83488; http://hdl.handle.net/10220/42599
• المؤسسة: Nanyang Technological University

A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.