[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides

[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides

A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.

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Bibliographic Details
Main Authors: Gandamana, Dhika Aditya, Tamura, Sayako, Demirelli, Mesut, Kaga, Atsushi, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2017
Subjects:
Donor–acceptor cyclopropanes
Vinyl azides
Online Access:https://hdl.handle.net/10356/83488
http://hdl.handle.net/10220/42599
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Institution: Nanyang Technological University
Language: English
Description
Summary:A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.

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