[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides

A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.

Saved in:

Bibliographic Details
Main Authors:	Gandamana, Dhika Aditya, Tamura, Sayako, Demirelli, Mesut, Kaga, Atsushi, Chiba, Shunsuke
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2017
Subjects:	Donor–acceptor cyclopropanes Vinyl azides
Online Access:	https://hdl.handle.net/10356/83488 http://hdl.handle.net/10220/42599
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-83488
record_format	dspace
spelling	sg-ntu-dr.10356-834882023-02-28T19:28:43Z [3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides Gandamana, Dhika Aditya Tamura, Sayako Demirelli, Mesut Kaga, Atsushi Chiba, Shunsuke School of Physical and Mathematical Sciences Donor–acceptor cyclopropanes Vinyl azides A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds. MOE (Min. of Education, S’pore) Accepted version 2017-06-06T09:06:26Z 2019-12-06T15:24:05Z 2017-06-06T09:06:26Z 2019-12-06T15:24:05Z 2017 Journal Article Kaga, A., Gandamana, D. A., Tamura, S., Demirelli, M., & Chiba, S. (2017). [3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides. Synlett, 28(09), 1091-1095. 0936-5214 https://hdl.handle.net/10356/83488 http://hdl.handle.net/10220/42599 10.1055/s-0036-1588703 en Synlett © 2017 Georg Thieme Verlag. This is the author created version of a work that has been peer reviewed and accepted for publication by Synlett, Georg Thieme Verlag. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1055/s-0036-1588703]. 4 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	Donor–acceptor cyclopropanes Vinyl azides
spellingShingle	Donor–acceptor cyclopropanes Vinyl azides Gandamana, Dhika Aditya Tamura, Sayako Demirelli, Mesut Kaga, Atsushi Chiba, Shunsuke [3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
description	A Sc(OTf)3-catalyzed reaction of vinyl azides with donor–acceptor cyclopropanes affords highly functionalized azidocyclopentanes in a diastereoselective fashion. The resulting azidocyclopentanes could be transformed into various cyclic scaffolds.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Gandamana, Dhika Aditya Tamura, Sayako Demirelli, Mesut Kaga, Atsushi Chiba, Shunsuke
format	Article
author	Gandamana, Dhika Aditya Tamura, Sayako Demirelli, Mesut Kaga, Atsushi Chiba, Shunsuke
author_sort	Gandamana, Dhika Aditya
title	[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
title_short	[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
title_full	[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
title_fullStr	[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
title_full_unstemmed	[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides
title_sort	[3+2] annulation of donor–acceptor cyclopropanes with vinyl azides
publishDate	2017
url	https://hdl.handle.net/10356/83488 http://hdl.handle.net/10220/42599
_version_	1759854576682401792

[3+2] Annulation of Donor–Acceptor Cyclopropanes with Vinyl Azides

Similar Items