Embedding a ruthenium-based structural mimic of the [Fe]-hydrogenase cofactor into papain

Embedding a ruthenium-based structural mimic of the [Fe]-hydrogenase cofactor into papain

We describe the synthesis of the ruthenacyclic carbamoyl complexes [Ru(2-NHC(O)C5H3NMe)(CO)2( o,o-Me2-C6H3S)(L)] (L = H2O or MeCN), which have a labile water or acetonitrile ligand at their sixth coordination sites. Steric bulk around the ruthenium center is essential in preventing isomerization and...

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Bibliographic Details
Main Authors: Barik, Chandan Kr, Ganguly, Rakesh, Li, Yongxin, Przybylski, Cédric, Salmain, Michèle, Leong, Weng Kee
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Science::Chemistry::Inorganic chemistry
Ruthenium
[Fe]- Hydrogenase
Online Access:https://hdl.handle.net/10356/136695
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/136695

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