Carboxylate, nitrate, sulfonate, and phosphate catalysts for living radical polymerization : via oxygen-iodine halogen bonding catalysis

• Main Authors: Mao, Weijia, Wang, Chen Gang, Lu, Yunpeng, Faustinelie, Winnie, Goto, Atsushi
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2020
• Subjects: Science::Chemistry; Radical Polymerization; BNOAc
• Online Access: https://hdl.handle.net/10356/137718
• Institution: Nanyang Technological University

Four families of oxyanions, i.e., carboxylate, nitrate, phosphate, and sulfonate, were studied as novel catalysts in living (or reversible deactivation) radical polymerization via oxygen-iodine halogen bonding catalysis. Oxyanions with sodium and tetraalkylammonium counter-cations exhibited good cat...