A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl

A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl

A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properti...

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Main Authors: Tokimaru, Yuki, Ito, Shingo, Nozaki, Kyoko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Azacorannulene
Buckybowls
Online Access:https://hdl.handle.net/10356/137722
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Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-137722
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spelling sg-ntu-dr.10356-1377222020-04-13T01:09:06Z A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl Tokimaru, Yuki Ito, Shingo Nozaki, Kyoko School of Physical and Mathematical Sciences Science::Chemistry Azacorannulene Buckybowls A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properties that arise from its large and highly curved π surface and the embedded nitrogen atom, which include association with C60, a lower LUMO level relative to azapentabenzocorannulene, and the formation of a radical cationic species upon oxidation. 2020-04-13T01:09:05Z 2020-04-13T01:09:05Z 2018 Journal Article Tokimaru, Y., Ito, S., & Nozaki, K. (2018). A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl. Angewandte Chemie International Edition, 57(31), 9818-9822. doi:10.1002/anie.201805678 1433-7851 https://hdl.handle.net/10356/137722 10.1002/anie.201805678 29878551 2-s2.0-85050452245 31 57 9818 9822 en Angewandte Chemie International Edition © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
topic Science::Chemistry
Azacorannulene
Buckybowls
spellingShingle Science::Chemistry
Azacorannulene
Buckybowls
Tokimaru, Yuki
Ito, Shingo
Nozaki, Kyoko
A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
description A highly curved nitrogen‐containing buckybowl, which can be considered as a corannulene/azacorannulene hybrid, was synthesized and characterized. This molecule has a polycyclic aromatic C40N core, corresponding to a partial azafullerene structure C80−xNx (x=1,2,3…), and exhibits interesting properties that arise from its large and highly curved π surface and the embedded nitrogen atom, which include association with C60, a lower LUMO level relative to azapentabenzocorannulene, and the formation of a radical cationic species upon oxidation.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tokimaru, Yuki
Ito, Shingo
Nozaki, Kyoko
format Article
author Tokimaru, Yuki
Ito, Shingo
Nozaki, Kyoko
author_sort Tokimaru, Yuki
title A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
title_short A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
title_full A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
title_fullStr A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
title_full_unstemmed A hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
title_sort hybrid of corannulene and azacorannulene : synthesis of a highly curved nitrogen‐containing buckybowl
publishDate 2020
url https://hdl.handle.net/10356/137722
_version_ 1681056645923209216

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