Metal‐free fast azidation by using tetrabutylammonium azide : effective synthesis of alkyl azides and well‐defined azido‐end polymethacrylates

• المؤلفون الرئيسيون: Wang, Chen-Gang, Chong, Amerlyn Ming Liing, Lu, Yunpeng, Liu, Xu, Goto, Atsushi
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Azides; Cycloaddition
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/137725
• المؤسسة: Nanyang Technological University

An effective method to synthesize azido‐end polymethacrylates from tetrabutylammonium azide (BNN3) in a nonpolar solvent (toluene) was developed. Several low‐mass alkyl halides were reacted with BNN3 in toluene as model reactions and the rate constants of these reactions were determined, to confirm...