Carbene-catalyzed dynamic kinetic resolution and asymmetric acylation of hydroxyphthalides and related natural products

A catalytic dynamic kinetic resolution and asymmetric acylation reaction of hydroxyphthalides is developed. The reaction involves formation of a carbene catalyst derived chiral acyl azolium intermediate that effectively differentiates the two enantiomers of racemic hydroxyphthalides. The method allo...

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Main Authors: Liu, Yingguo, Majhi, Pankaj Kumar, Song, Runjiang, Mou, Chengli, Hao, Lin, Chai, Huifang, Jin, Zhichao, Chi, Robin Yonggui
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2020
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在線閱讀:https://hdl.handle.net/10356/137896
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