Arsenene nanoribbon edge-resolved strong magnetism

• المؤلفون الرئيسيون: Wang, Sanmei, Zhang, Xi, Huang, Yongli, Sun, Chang Qing
• مؤلفون آخرون: School of Electrical and Electronic Engineering
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Engineering::Electrical and electronic engineering; Arsenene; Magnetism
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/138290
• المؤسسة: Nanyang Technological University

We proposed a mechanism to induce strong magnetism of up to 10.92 emu g-1 in hexagonal-phase arsenene nanoribbon (AsNR) from the perspective of edge quantum entrapment. Consistency between bond-order-length-strength correlation (BOLS) theory and density functional theory (DFT) calculations verified that: (i) the edge bond contraction of 9.54% deepened the edge potential well of AsNR, (ii) a net charge of 0.06 e- transferred from the inner region to the edge; and (iii) the edge quantum well polarized the unpaired electron and the net spin (antiferromagnetic or ferromagnetic depending on the width) is localized at the zigzag edge. The finding sheds a light on applications of AsNR in magnetic storage devices.