Activation of dihydrogen by 1,4,2,5-diazadiborinine
Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS ana...
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sg-ntu-dr.10356-1385552020-05-08T04:29:03Z Activation of dihydrogen by 1,4,2,5-diazadiborinine Wang, Baolin Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition. MOE (Min. of Education, S’pore) 2020-05-08T04:29:03Z 2020-05-08T04:29:03Z 2018 Journal Article Wang, B., & Kinjo, R. (2018). Activation of dihydrogen by 1,4,2,5-diazadiborinine. Tetrahedron, 74(51), 7273-7276. doi:10.1016/j.tet.2018.10.067 0040-4020 https://hdl.handle.net/10356/138555 10.1016/j.tet.2018.10.067 2-s2.0-85055907392 51 74 7273 7276 en Tetrahedron © 2018 Elsevier Ltd . All rights reserved. |
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Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation |
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Science::Chemistry 1,4,2,5-Diazadiborinine Dihydrogen Activation Wang, Baolin Kinjo, Rei Activation of dihydrogen by 1,4,2,5-diazadiborinine |
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Activation of dihydrogen (H2) by 1,4,2,5-diazadiborinine is reported. Under the heating condition, treatment of 1,4,2,5-diazadiborinine with H2 results in the cleavage of H–H bond, to afford product 2, which was fully characterized by NMR and IR spectroscopy as well as X-ray diffraction and HRMS analysis. In the presence of borane dimethylsulfide complex (BH3·SMe2), 2 readily isomerizes to 3 under the mild reaction condition. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Wang, Baolin Kinjo, Rei |
| format |
Article |
| author |
Wang, Baolin Kinjo, Rei |
| author_sort |
Wang, Baolin |
| title |
Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_short |
Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_full |
Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_fullStr |
Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_full_unstemmed |
Activation of dihydrogen by 1,4,2,5-diazadiborinine |
| title_sort |
activation of dihydrogen by 1,4,2,5-diazadiborinine |
| publishDate |
2020 |
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https://hdl.handle.net/10356/138555 |
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1681058912211566592 |