The difference Se makes : a bio-inspired dppf-supported nickel selenolate complex boosts dihydrogen evolution with high oxygen tolerance

The difference Se makes : a bio-inspired dppf-supported nickel selenolate complex boosts dihydrogen evolution with high oxygen tolerance

Inspired by the metal active sites of [NiFeSe]-hydrogenases, a dppf-supported nickel(II) selenolate complex (dppf=1,1'-bis(diphenylphosphino)ferrocene) shows high catalytic activity for electrochemical proton reduction with a remarkable enzyme-like H2 evolution turnover frequency (TOF) of 7838 ...

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Bibliographic Details
Main Authors: Pan, Zhong-Hua, Tao, Yun-Wen, He, Quan-Feng, Wu, Qiao-Yu, Cheng, Li-Ping, Wei, Zhan-Hua, Wu, Ji-Huai, Lin, Jin-Qing, Sun, Di, Zhang, Qi-Chun, Tian, Dan, Luo, Geng-Geng
Other Authors: School of Materials Science & Engineering
Format: Article
Language:English
Published: 2020
Subjects:
Engineering::Materials
DFT Calculations
Dihydrogen Evolution
Online Access:https://hdl.handle.net/10356/139416
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Institution: Nanyang Technological University
Language: English

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https://hdl.handle.net/10356/139416

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