The difference Se makes : a bio-inspired dppf-supported nickel selenolate complex boosts dihydrogen evolution with high oxygen tolerance

• Main Authors: Pan, Zhong-Hua, Tao, Yun-Wen, He, Quan-Feng, Wu, Qiao-Yu, Cheng, Li-Ping, Wei, Zhan-Hua, Wu, Ji-Huai, Lin, Jin-Qing, Sun, Di, Zhang, Qi-Chun, Tian, Dan, Luo, Geng-Geng
• Other Authors: School of Materials Science & Engineering
• Format: Article
• Language: English
• Published: 2020
• Subjects: Engineering::Materials; DFT Calculations; Dihydrogen Evolution
• Online Access: https://hdl.handle.net/10356/139416
• Institution: Nanyang Technological University

Inspired by the metal active sites of [NiFeSe]-hydrogenases, a dppf-supported nickel(II) selenolate complex (dppf=1,1'-bis(diphenylphosphino)ferrocene) shows high catalytic activity for electrochemical proton reduction with a remarkable enzyme-like H2 evolution turnover frequency (TOF) of 7838 ...