Catalytic asymmetric conjugate arylation of γ,δ-unsaturated β-dicarbonyl compounds

• المؤلفون الرئيسيون: Yao, Jian, Yin, Long, Shen, Yue, Lu, Tao, Hayashi, Tamio, Dou, Xiaowei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2020
• الموضوعات: Science::Chemistry; Catalysts; Hydrocarbons
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/138739

The first catalytic asymmetric conjugate addition to γ,δ-unsaturated β-dicarbonyl compounds was developed. With a chiral diene-rhodium(I) μ-chloro dimer as the catalyst in toluene/H2O, asymmetric conjugate arylation of γ,δ-unsaturated β-dicarbonyl compounds with arylboronic acids proceeded in high e...