Reactivity of a base-stabilized germanium(I) dimer toward group 9 metal(I) chloride and dimanganese decacarbonyl

• Main Authors: Muhammad Luthfi Ismail, Liu, Fu-Quan, Yim, Wai-Leung, Ganguly, Rakesh, Li, Yongxin, So, Cheuk-Wai
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2020
• Subjects: Science::Chemistry; Ligands; Oligomers
• Online Access: https://hdl.handle.net/10356/139491
• Institution: Nanyang Technological University

The reactivity of the 2-imino-5,6-methylenedioxylphenylgermanium(I) dimer toward group 9 metal(I) chloride and dimanganese decacarbonyl is described. [LGe:]2 (1, L = 2-imino-5,6-methylenedioxylphenyl) underwent a disproportionation reaction with 1.5 equiv of group 9 metal(I) chloride [MCl(cod)]2 (M...