NHC catalyzed enantioselective Coates-Claisen rearrangement : a rapid access to the dihydropyran core for oleuropein based secoiridoids

NHC catalyzed enantioselective Coates-Claisen rearrangement : a rapid access to the dihydropyran core for oleuropein based secoiridoids

We present the short synthesis of the suitably functionalized enantioselective dihydropyran core of secoiridoids using an N-heterocyclic carbene (NHC) catalyzed Coates-Claisen rearrangement mechanism. The key steps of the synthesis are (i) the highly enantioselective NHC catalyzed Coates-Claisen rea...

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Bibliographic Details
Main Authors: Vedachalam, Seenuvasan, Murugesh, Nithya, Chakraborty, Priyanka, Karvembu, Ramasamy, Liu, Xue-Wei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry
Coates-Claisen
Oleuropein
Online Access:https://hdl.handle.net/10356/142696
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/142696

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