NHC catalyzed enantioselective Coates-Claisen rearrangement : a rapid access to the dihydropyran core for oleuropein based secoiridoids
We present the short synthesis of the suitably functionalized enantioselective dihydropyran core of secoiridoids using an N-heterocyclic carbene (NHC) catalyzed Coates-Claisen rearrangement mechanism. The key steps of the synthesis are (i) the highly enantioselective NHC catalyzed Coates-Claisen rea...
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Main Authors: | Vedachalam, Seenuvasan, Murugesh, Nithya, Chakraborty, Priyanka, Karvembu, Ramasamy, Liu, Xue-Wei |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/142696 |
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Institution: | Nanyang Technological University |
Language: | English |
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