Superbase-catalyzed stereo- and regioselective glycosylation with 2‑nitroglycals : facile access to 2‑amino-2-deoxy‑O‑glycosides

• Main Authors: Pal, Kumar Bhaskar, Guo, Aoxin, Das, Mrinmoy, Báti, Gábor, Liu, Xue-Wei
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2020
• Subjects: Science::Chemistry; 2-Nitroglycals; Superbase
• Online Access: https://hdl.handle.net/10356/144910
• Institution: Nanyang Technological University

An efficient superbase-catalyzed stereo- and regio-selective glycosylation of 2-nitroglycals with high functional group compatibility is reported. The ion pair generated from alcohol and a catalytic amount of P4-t-Bu was vital for the successful implementation of this stereoselective glycosylation und...