Germylone-bridged bimetallic Ir and Rh complexes

Germylone-bridged bimetallic Ir and Rh complexes

The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge...

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Bibliographic Details
Main Authors: Su, Bochao, Ota, Kei, Li, Yongxin, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Germylone
Bimetallic Complexes
Online Access:https://hdl.handle.net/10356/146216
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Institution: Nanyang Technological University
Language: English
Description
Summary:The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh–Ge–Rh–Ge–Rh chain was also synthesized.

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