Germylone-bridged bimetallic Ir and Rh complexes
The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge...
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sg-ntu-dr.10356-1462162023-02-28T19:32:56Z Germylone-bridged bimetallic Ir and Rh complexes Su, Bochao Ota, Kei Li, Yongxin Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry Germylone Bimetallic Complexes The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh–Ge–Rh–Ge–Rh chain was also synthesized. Ministry of Education (MOE) Nanyang Technological University Accepted version We are grateful to Nanyang Technological University (NTU) and the Singapore Ministry of Education (MOE2017-T1-002-031) for financial support. 2021-02-02T07:18:06Z 2021-02-02T07:18:06Z 2019 Journal Article Su, B., Ota, K., Li, Y., & Kinjo, R. (2019). Germylone-bridged bimetallic Ir and Rh complexes. Dalton Transactions, 48(11), 3555-3559. doi:10.1039/C9DT00145J 1477-9226 https://hdl.handle.net/10356/146216 10.1039/C9DT00145J 11 48 3555 3559 en Dalton Transactions © 2019 The Author(s) (Royal Society of Chemistry). All rights reserved. This paper was published in Dalton Transactions and is made available with permission of The Author(s) (Royal Society of Chemistry). application/pdf |
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Science::Chemistry Germylone Bimetallic Complexes |
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Science::Chemistry Germylone Bimetallic Complexes Su, Bochao Ota, Kei Li, Yongxin Kinjo, Rei Germylone-bridged bimetallic Ir and Rh complexes |
| description |
The reactions of germylone 1 with one equivalent of [M(COD)Cl]2 (M = Ir, Rh) afforded the germylone-bridged bimetallic complexes 2 and 3, which have been spectroscopically and structurally characterized. Density functional theory (DFT) studies reveal the relatively strong interactions between the Ge atom and these metals. By the reaction of [Rh(COD)Cl]2 with CO followed by addition of 1, a complex 4 involving a Rh–Ge–Rh–Ge–Rh chain was also synthesized. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Su, Bochao Ota, Kei Li, Yongxin Kinjo, Rei |
| format |
Article |
| author |
Su, Bochao Ota, Kei Li, Yongxin Kinjo, Rei |
| author_sort |
Su, Bochao |
| title |
Germylone-bridged bimetallic Ir and Rh complexes |
| title_short |
Germylone-bridged bimetallic Ir and Rh complexes |
| title_full |
Germylone-bridged bimetallic Ir and Rh complexes |
| title_fullStr |
Germylone-bridged bimetallic Ir and Rh complexes |
| title_full_unstemmed |
Germylone-bridged bimetallic Ir and Rh complexes |
| title_sort |
germylone-bridged bimetallic ir and rh complexes |
| publishDate |
2021 |
| url |
https://hdl.handle.net/10356/146216 |
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