Asymmetric stepwise reductive amination of sulfonamides, sulfamates, and a phosphinamide by nickel catalysis

Asymmetric stepwise reductive amination of sulfonamides, sulfamates, and a phosphinamide by nickel catalysis

Asymmetric reductive amination of poorly nucleophilic sulfonamides was realized in the presence of nickel catalysts and titanium alkoxide. A wide range of ketones, including enolizable ketones and some biaryl ones, were converted into sulfonamides in excellent enantiomeric excess. The cyclization of...

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Bibliographic Details
Main Authors: Zhao, Xiaohu, Xu, Haiyan, Huang, Xiaolei, Zhou, Steve Jianrong
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Chiral Alkylamines
Nickel Catalysis
Online Access:https://hdl.handle.net/10356/146874
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/146874

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