Direct laser patterning of a 2D WSe2 logic circuit

Carrier doping is the basis of the modern semiconductor industry. Great efforts are put into the control of carrier doping for 2D semiconductors, especially the layered transition metal dichalcogenides. Here, the direct laser patterning of WSe2 devices via light‐induced hole doping is systematically...

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Main Authors: Zhu, Chao, Zhao, Xiaoxu, Wang, Xiaowei, Chen, Jieqiong, Yu, Peng, Liu, Song, Zhou, Jiadong, Fu, Qundong, Zeng, Qingsheng, He, Yongmin, Edgar, James H., Pennycook, Stephen J., Liu, Fucai, Liu, Zheng
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2021
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Online Access:https://hdl.handle.net/10356/148303
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Institution: Nanyang Technological University
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spelling sg-ntu-dr.10356-1483032023-07-14T16:02:44Z Direct laser patterning of a 2D WSe2 logic circuit Zhu, Chao Zhao, Xiaoxu Wang, Xiaowei Chen, Jieqiong Yu, Peng Liu, Song Zhou, Jiadong Fu, Qundong Zeng, Qingsheng He, Yongmin Edgar, James H. Pennycook, Stephen J. Liu, Fucai Liu, Zheng School of Materials Science and Engineering School of Electrical and Electronic Engineering Sun Yat‐sen University Kansas State University National University of Singapore University of Electronic Science and Technology of China CNRS International NTU THALES Research Alliances Engineering::Materials::Microelectronics and semiconductor materials Controllable Doping Direct Laser Patterning Carrier doping is the basis of the modern semiconductor industry. Great efforts are put into the control of carrier doping for 2D semiconductors, especially the layered transition metal dichalcogenides. Here, the direct laser patterning of WSe2 devices via light‐induced hole doping is systematically studied. By changing the laser power, scan speed, and the number of irradiation times, different levels of hole doping can be achieved in the pristine electron‐transport‐dominated WSe2, without obvious sample thinning. Scanning transmission electron microscopy characterization reveals that the oxidation of the laser‐radiated WSe2 is the origin of the carrier doping. Photocurrent mapping shows that after the same amount of laser irradiation, with increasing thickness, the laser patterned PN junction changes from the pure lateral to the vertical‐lateral hybrid structure, accompanied by the decrease in the open circuit voltage. The vertical‐lateral hybrid PN junction can be tuned to a pure lateral one by further irradiation, showing possibilities to construct complex junction profiles. Moreover, a NOR gate circuit is demonstrated by direct patterning of p‐doped channels using laser irradiation without introducing passive layers and metal electrodes with different work functions. This method simplifies device fabrication procedures and shows a promising future in large scale logic circuit applications. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) National Research Foundation (NRF) Accepted version 2021-05-17T06:13:52Z 2021-05-17T06:13:52Z 2021 Journal Article Zhu, C., Zhao, X., Wang, X., Chen, J., Yu, P., Liu, S., Zhou, J., Fu, Q., Zeng, Q., He, Y., Edgar, J. H., Pennycook, S. J., Liu, F. & Liu, Z. (2021). Direct laser patterning of a 2D WSe2 logic circuit. Advanced Functional Materials. https://dx.doi.org/10.1002/adfm.202009549 1616-3028 https://hdl.handle.net/10356/148303 10.1002/adfm.202009549 en NRF‐CRP21‐2018‐0007 NRF‐CRP22‐2019‐0007 MOE2016‐T2‐1‐131 MOE2018‐T3‐1‐002 MOE Tier 1 (RG4/17) MOE Tier 1 (RG7/18) MOE2017‐T2‐2‐139 Applied Basic Research Program of Sichuan Province. Grant Number: 2020ZYD014 US National Science Foundation. Grant Number: 1538127 A*STAR A2083c0052 Advanced Functional Materials This is the accepted version of the following article: Zhu, C., Zhao, X., Wang, X., Chen, J., Yu, P., Liu, S., Zhou, J., Fu, Q., Zeng, Q., He, Y., Edgar, J. H., Pennycook, S. J., Liu, F. & Liu, Z. (2021). Direct laser patterning of a 2D WSe2 logic circuit. Advanced Functional Materials. https://dx.doi.org/10.1002/adfm.202009549, which has been published in final form at https://doi.org/10.1002/adfm.202009549. This article may be used for non-commercial purposes in accordance with the Wiley Self-Archiving Policy [https://authorservices.wiley.com/authorresources/Journal-Authors/licensing/self-archiving.html]. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering::Materials::Microelectronics and semiconductor materials
Controllable Doping
Direct Laser Patterning
spellingShingle Engineering::Materials::Microelectronics and semiconductor materials
Controllable Doping
Direct Laser Patterning
Zhu, Chao
Zhao, Xiaoxu
Wang, Xiaowei
Chen, Jieqiong
Yu, Peng
Liu, Song
Zhou, Jiadong
Fu, Qundong
Zeng, Qingsheng
He, Yongmin
Edgar, James H.
Pennycook, Stephen J.
Liu, Fucai
Liu, Zheng
Direct laser patterning of a 2D WSe2 logic circuit
description Carrier doping is the basis of the modern semiconductor industry. Great efforts are put into the control of carrier doping for 2D semiconductors, especially the layered transition metal dichalcogenides. Here, the direct laser patterning of WSe2 devices via light‐induced hole doping is systematically studied. By changing the laser power, scan speed, and the number of irradiation times, different levels of hole doping can be achieved in the pristine electron‐transport‐dominated WSe2, without obvious sample thinning. Scanning transmission electron microscopy characterization reveals that the oxidation of the laser‐radiated WSe2 is the origin of the carrier doping. Photocurrent mapping shows that after the same amount of laser irradiation, with increasing thickness, the laser patterned PN junction changes from the pure lateral to the vertical‐lateral hybrid structure, accompanied by the decrease in the open circuit voltage. The vertical‐lateral hybrid PN junction can be tuned to a pure lateral one by further irradiation, showing possibilities to construct complex junction profiles. Moreover, a NOR gate circuit is demonstrated by direct patterning of p‐doped channels using laser irradiation without introducing passive layers and metal electrodes with different work functions. This method simplifies device fabrication procedures and shows a promising future in large scale logic circuit applications.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Zhu, Chao
Zhao, Xiaoxu
Wang, Xiaowei
Chen, Jieqiong
Yu, Peng
Liu, Song
Zhou, Jiadong
Fu, Qundong
Zeng, Qingsheng
He, Yongmin
Edgar, James H.
Pennycook, Stephen J.
Liu, Fucai
Liu, Zheng
format Article
author Zhu, Chao
Zhao, Xiaoxu
Wang, Xiaowei
Chen, Jieqiong
Yu, Peng
Liu, Song
Zhou, Jiadong
Fu, Qundong
Zeng, Qingsheng
He, Yongmin
Edgar, James H.
Pennycook, Stephen J.
Liu, Fucai
Liu, Zheng
author_sort Zhu, Chao
title Direct laser patterning of a 2D WSe2 logic circuit
title_short Direct laser patterning of a 2D WSe2 logic circuit
title_full Direct laser patterning of a 2D WSe2 logic circuit
title_fullStr Direct laser patterning of a 2D WSe2 logic circuit
title_full_unstemmed Direct laser patterning of a 2D WSe2 logic circuit
title_sort direct laser patterning of a 2d wse2 logic circuit
publishDate 2021
url https://hdl.handle.net/10356/148303
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