A base-stabilized silylene-promoted C(sp³)-H borylation and H₂ activation

• المؤلفون الرئيسيون: Khoo, Sabrina, Siu, Chi-Kit, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry::Inorganic chemistry; Silylene Compound; Dihydrogen
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/149971

Treatment of the amidinato amidosilylene [L{(Me3Si)2N}Si:] [1, L = PhC(NtBu)2] with a slight excess of borane-tetrahydrofuran complex [BH3·THF] in toluene at room temperature afforded the silylene-borane adduct [L{(Me3Si)2N}Si:→BH3] (2). A triflate substituent was introduced on the boron center by r...