A base-stabilized silylene-promoted C(sp³)-H borylation and H₂ activation
Treatment of the amidinato amidosilylene [L{(Me3Si)2N}Si:] [1, L = PhC(NtBu)2] with a slight excess of borane-tetrahydrofuran complex [BH3·THF] in toluene at room temperature afforded the silylene-borane adduct [L{(Me3Si)2N}Si:→BH3] (2). A triflate substituent was introduced on the boron center by r...
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| Main Authors: | , , |
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| 格式: | Article |
| 語言: | English |
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2021
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| 在線閱讀: | https://hdl.handle.net/10356/149971 |
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