Palladium-catalyzed anti-michael reductive heck reaction of α,β-unsaturated esters

• المؤلفون الرئيسيون: Guo, Tao, Ding, Yalan, Zhou, Lili, Xu, Haiyan, Loh, Teck-Peng, Wu, Xiaojin
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Reductive Heck Reaction; Anti-Michael Selectivity
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/154741
• المؤسسة: Nanyang Technological University

A general intermolecular anti-Michael reductive Heck reaction of α,β-unsaturated esters with organobromides has been developed. Most topical classes of aryl, heteroaryl, and vinyl bromides were found to efficiently react with a variety of internal conjugated alkenes. This protocol set up a platform...