Diastereoselective intramolecular hydride transfer triggered by electrophilic halogenation of aryl alkenes

Diastereoselective intramolecular hydride transfer triggered by electrophilic halogenation of aryl alkenes

Diastereoselective hydride transfer could be triggered by electrophilic halogenation (bromination or fluorination) of homoallylic alcohol O-Bn ethers. The resulting diastereomerically enriched haloalkyl alcohols underwent subsequent intramolecular nucleophilic substitution to afford the correspondin...

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Bibliographic Details
Main Authors: Wang, Bin, Gandamana, Dhika Aditya, León Rayo, David Fabian, Gagosz, Fabien, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Tetrahydrofurans
Hydrocarbons
Online Access:https://hdl.handle.net/10356/154839
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Institution: Nanyang Technological University
Language: English
Description
Summary:Diastereoselective hydride transfer could be triggered by electrophilic halogenation (bromination or fluorination) of homoallylic alcohol O-Bn ethers. The resulting diastereomerically enriched haloalkyl alcohols underwent subsequent intramolecular nucleophilic substitution to afford the corresponding tetrahydrofurans.

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