Leveraging of sulfur anions in photoinduced molecular transformations

Leveraging of sulfur anions in photoinduced molecular transformations

This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interacti...

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Bibliographic Details
Main Authors: Li, Haoyu, Liu, Yuliang, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Sulfur Anions
Single-Electron Transfer
Online Access:https://hdl.handle.net/10356/154869
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Institution: Nanyang Technological University
Language: English
Description
Summary:This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.

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