Leveraging of sulfur anions in photoinduced molecular transformations

Leveraging of sulfur anions in photoinduced molecular transformations

This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interacti...

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Main Authors: Li, Haoyu, Liu, Yuliang, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Sulfur Anions
Single-Electron Transfer
Online Access:https://hdl.handle.net/10356/154869
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1548692023-02-28T19:59:24Z Leveraging of sulfur anions in photoinduced molecular transformations Li, Haoyu Liu, Yuliang Chiba, Shunsuke School of Physical and Mathematical Sciences Science::Chemistry Sulfur Anions Single-Electron Transfer This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions. Nanyang Technological University Published version This work was supported by funding from Nanyang Technological University (NTU). 2022-01-17T04:35:12Z 2022-01-17T04:35:12Z 2021 Journal Article Li, H., Liu, Y. & Chiba, S. (2021). Leveraging of sulfur anions in photoinduced molecular transformations. JACS Au, 1(12), 2121-2129. https://dx.doi.org/10.1021/jacsau.1c00363 2691-3704 https://hdl.handle.net/10356/154869 10.1021/jacsau.1c00363 34977884 12 1 2121 2129 en JACS Au © 2021 The Authors. Published by American Chemical Society. This is an open-access article distributed under the terms of the Creative Commons Attribution License. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Sulfur Anions
Single-Electron Transfer
spellingShingle Science::Chemistry
Sulfur Anions
Single-Electron Transfer
Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
Leveraging of sulfur anions in photoinduced molecular transformations
description This perspective describes recent advances in the use of sulfur anions to promote molecular transformations under irradiation with visible light. The topics are classified by the following reaction modes performed by the key sulfur anions: (1) C-S coupling via electron donor-acceptor (EDA) interactions, (2) photoinduced molecular transformation via sulfur anion EDA catalysis, (3) sulfur anions as photoredox and hydrogen atom transfer (HAT) catalysts, and 4) dithiocarbamate and xanthate as nucleophilic catalysts for photoinduced radical cascade reactions.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
format Article
author Li, Haoyu
Liu, Yuliang
Chiba, Shunsuke
author_sort Li, Haoyu
title Leveraging of sulfur anions in photoinduced molecular transformations
title_short Leveraging of sulfur anions in photoinduced molecular transformations
title_full Leveraging of sulfur anions in photoinduced molecular transformations
title_fullStr Leveraging of sulfur anions in photoinduced molecular transformations
title_full_unstemmed Leveraging of sulfur anions in photoinduced molecular transformations
title_sort leveraging of sulfur anions in photoinduced molecular transformations
publishDate 2022
url https://hdl.handle.net/10356/154869
_version_ 1759854510494187520

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