Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction

• المؤلفون الرئيسيون: Zhu, Daoyong, Xu, Wenqiang, Pu, Maoping, Wu, Yun-Dong, Chi, Robin Yonggui, Zhou, Steve Jianrong
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Palladium; Hydrocarbons
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/155069

Palladium catalyzes a domino Heck arylation and alkylation of nonconjugated cyclodienes to produce trans isomers of disubstituted cyclohexenes in exceptionally high enantiomeric ratios, reaching 100:1 to 200:1 in many cases. Importantly, the interactions of the two CF bonds of Josiphos and the sodiu...