Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction

Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction

Palladium catalyzes a domino Heck arylation and alkylation of nonconjugated cyclodienes to produce trans isomers of disubstituted cyclohexenes in exceptionally high enantiomeric ratios, reaching 100:1 to 200:1 in many cases. Importantly, the interactions of the two CF bonds of Josiphos and the sodiu...

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Main Authors: Zhu, Daoyong, Xu, Wenqiang, Pu, Maoping, Wu, Yun-Dong, Chi, Robin Yonggui, Zhou, Steve Jianrong
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2022
主題:
Science::Chemistry
Palladium
Hydrocarbons
在線閱讀:https://hdl.handle.net/10356/155069
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機構: Nanyang Technological University
語言: English

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