Fragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anion

The stable cyclic (alkyl)(amino)alumanyl anion (CAAAl) 3 reacts with white phosphorus (P4) under ambient conditions, in which P4is fragmented into a P1unit to afford the bis(alumanyl)phosphide 2, demonstrating the direct formation of a P anion from an Al anion. Structural and electronic features of...

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Bibliographic Details
Main Authors: Koshino, Kota, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/155199
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Institution: Nanyang Technological University
Language: English
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