Fragmentation of white phosphorus by a cyclic (alkyl)(amino)alumanyl anion
The stable cyclic (alkyl)(amino)alumanyl anion (CAAAl) 3 reacts with white phosphorus (P4) under ambient conditions, in which P4is fragmented into a P1unit to afford the bis(alumanyl)phosphide 2, demonstrating the direct formation of a P anion from an Al anion. Structural and electronic features of...
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| Main Authors: | , |
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| 格式: | Article |
| 語言: | English |
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2022
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| 在線閱讀: | https://hdl.handle.net/10356/155199 |
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| 機構: | Nanyang Technological University |
| 語言: | English |