Iodo(III)-Meyer-Schuster rearrangement of propargylic alcohols promoted by benziodoxole triflate

Iodo(III)-Meyer-Schuster rearrangement of propargylic alcohols promoted by benziodoxole triflate

Benziodoxole triflate (BXT), a cyclic iodine(III) electrophile, has been found to promote a rearrangement of propargylic alcohols into α,β-unsaturated ketones bearing an α-λ3-iodanyl group. This iodo(III)-Meyer-Schuster rearrangement proceeds under mild conditions and tolerates a variety of function...

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Bibliographic Details
Main Authors: Laskar, Roshayed Ali, Ding, Wei, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Benziodoxole Triflate
Unsaturated Ketones
Online Access:https://hdl.handle.net/10356/160362
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/160362

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