Rotation of a helical coordination polymer by mechanical grinding

Rotation of a helical coordination polymer by mechanical grinding

Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction...

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Bibliographic Details
Main Authors: Rath, Bibhuti Bhusan, Kole, Goutam Kumar, Morris, Samuel Alexander, Vittal, Jagadese J.
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Metal-Complex
Mechanochemistry
Online Access:https://hdl.handle.net/10356/160878
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Institution: Nanyang Technological University
Language: English
Description
Summary:Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield.

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