Rotation of a helical coordination polymer by mechanical grinding

Rotation of a helical coordination polymer by mechanical grinding

Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction...

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Main Authors: Rath, Bibhuti Bhusan, Kole, Goutam Kumar, Morris, Samuel Alexander, Vittal, Jagadese J.
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Metal-Complex
Mechanochemistry
Online Access:https://hdl.handle.net/10356/160878
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1608782022-08-05T02:58:44Z Rotation of a helical coordination polymer by mechanical grinding Rath, Bibhuti Bhusan Kole, Goutam Kumar Morris, Samuel Alexander Vittal, Jagadese J. School of Materials Science and Engineering Science::Chemistry Metal-Complex Mechanochemistry Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield. Ministry of Education (MOE) This work was financially supported by the Ministry of Education, Singapore (Grant No. Tier 1 WBS R-143-000-A12-114 and R-143-000-B13-114). 2022-08-05T02:58:44Z 2022-08-05T02:58:44Z 2020 Journal Article Rath, B. B., Kole, G. K., Morris, S. A. & Vittal, J. J. (2020). Rotation of a helical coordination polymer by mechanical grinding. Chemical Communications, 56(46), 6289-6292. https://dx.doi.org/10.1039/D0CC02158J 1359-7345 https://hdl.handle.net/10356/160878 10.1039/D0CC02158J 46 56 6289 6292 en WBS R-143-000-A12-114 R-143-000-B13-114 Chemical Communications © 2020 The Royal Society of Chemistry. All rights reserved.
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Metal-Complex
Mechanochemistry
spellingShingle Science::Chemistry
Metal-Complex
Mechanochemistry
Rath, Bibhuti Bhusan
Kole, Goutam Kumar
Morris, Samuel Alexander
Vittal, Jagadese J.
Rotation of a helical coordination polymer by mechanical grinding
description Anisotropic cell volume expansion by mechanical grinding of the solid facilitates the concerted rotation of the photo-inert helical coordination polymer, which causes the misaligned arms containing olefin functional groups in the neighbouring strands to align to undergo [2+2] cycloaddition reaction in 83% yield.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Rath, Bibhuti Bhusan
Kole, Goutam Kumar
Morris, Samuel Alexander
Vittal, Jagadese J.
format Article
author Rath, Bibhuti Bhusan
Kole, Goutam Kumar
Morris, Samuel Alexander
Vittal, Jagadese J.
author_sort Rath, Bibhuti Bhusan
title Rotation of a helical coordination polymer by mechanical grinding
title_short Rotation of a helical coordination polymer by mechanical grinding
title_full Rotation of a helical coordination polymer by mechanical grinding
title_fullStr Rotation of a helical coordination polymer by mechanical grinding
title_full_unstemmed Rotation of a helical coordination polymer by mechanical grinding
title_sort rotation of a helical coordination polymer by mechanical grinding
publishDate 2022
url https://hdl.handle.net/10356/160878
_version_ 1743119551766200320

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