Upcycling end of life solar panels to lithium-ion batteries via a low temperature approach

• Main Authors: Tay, Yeow Boon, Sim, Ying, Ang, Jeremy Koon Keong, Muhammad Iszaki Patdillah, Chua, Huei Min, Tang, Ernest Jun Jie, Srinivasan, Madhavi, Mathews, Nripan
• Other Authors: School of Materials Science and Engineering
• Format: Article
• Language: English
• Published: 2022
• Subjects: Engineering::Environmental engineering::Waste management; Engineering::Materials::Energy materials; Upcycling; Solar Panel; Lithium-Ion Batteries; Silicon Anode; Low Temperature
• Online Access: https://hdl.handle.net/10356/160911
• Institution: Nanyang Technological University

The massive adoption of renewable energy especially photovoltaic (PVs) panel is expected to create a huge waste stream once it reaches end-of-life (EoL). Despite having the highest embodied energy, present photovoltaic recycling neglected the high purity silicon found in the PV cell. Herein, a scalable and low energy process was developed to recover pristine silicon from EoL solar panel through a process which avoids energy-intensive high temperature processes. The extracted silicon was upcycled to form lithium-ion battery anodes with performances comparable to as-purchased silicon. The anodes retained 87.5 % capacity after 200 cycles while maintaining high coulombic efficiency (>99 %) at 0.5 Ag -1 charging rate. This simple and scalable process to upcycle EoL-solar panels into high value silicon-based anode can narrow the gap towards net-zero waste economy.