Metal-catalyzed transformations of cyclopropanols via homoenolates

• المؤلفون الرئيسيون: Sekiguchi, Yoshiya, Yoshikai, Naohiko
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Cyclopropanols; Transition Metal Catalysis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/161230
• المؤسسة: Nanyang Technological University

Metal homoenolates represent uniquely useful organometallic intermediates in synthetic chemistry, allowing umpolung synthesis of β-functionalized carbonyl compounds. While siloxycyclopropanes had been established as reliable precursors to homoenolates, often stoichiometric, for diverse carboncarbon...