Chalcogen bond-guided conformational isomerization enables catalytic dynamic kinetic resolution of sulfoxides

• المؤلفون الرئيسيون: Liu, Jianjian, Zhou, Mali, Deng, Rui, Zheng, Pengcheng, Chi, Robin Yonggui
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Chalcogen Bonding; Catalysis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/161382

Conformational isomerization can be guided by weak interactions such as chalcogen bonding (ChB) interactions. Here we report a catalytic strategy for asymmetric access to chiral sulfoxides by employing conformational isomerization and chalcogen bonding interactions. The reaction involves a sulfoxide...