Synthesis of a π-extended azacorannulenophane enabled by strain-induced 1,3-dipolar cycloaddition

• المؤلفون الرئيسيون: Zhang, Xinjiang, Mackinnon, Marc R., Bodwell, Graham J., Ito, Shingo
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Azacorannulenes; Cycloadditions
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/161664

The first example of a cyclophane bearing a nitrogen-containing buckybowl was synthesized via sequential 1,3-dipolar cycloaddition and palladium-catalyzed intramolecular cyclization. The key to the successful synthesis is the strain-induced 1,3-dipolar cycloaddition of a polycyclic aromatic azomethi...