Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions

• Main Authors: Seah, Jeffery Wee Kiong, Teo, Ronald Hong Xiang, Leung, Pak-Hing
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2022
• Subjects: Science::Chemistry; Chiral Auxiliaries; Hydrophosphination
• Online Access: https://hdl.handle.net/10356/162238
• Institution: Nanyang Technological University

A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient catalysts for asymmetric hydrophosphination reactions. In all cases, the chiral auxiliaries remained coordinated to the palladium centres throughout the course of the reactions. Despite the presence of...