Coordination of the hemilabile ligand diphenylvinylphosphine to Ru4(µ-H)4(CO)12: synthesis, stability and structural studies
The tetraruthenium tetrahydrido carbonyl cluster Ru4(µ-H)4(CO)12 (1) reacts with diphenylvinylphosphine under thermal activation to give the substitution products Ru4(µ-H)4(CO)12−n(κ1-Ph2PCH=CH2)n, (2) (n = 3 (a); 4 (b)). Both 2a and 2b have been completely characterized, including by single-crystal...
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Main Authors: | Neo, Edward Ren Kai, Ong, Han Wee, Wong, Zhen Xuan, Kumaran, Elumalai, Ganguly, Rakesh, Leong, Weng Kee, Tan, Kelvin Yong Leng |
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其他作者: | School of Physical and Mathematical Sciences |
格式: | Article |
語言: | English |
出版: |
2022
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主題: | |
在線閱讀: | https://hdl.handle.net/10356/162440 |
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機構: | Nanyang Technological University |
語言: | English |
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