Bilateral aromatic extension of corannulene nucleus

• المؤلفون الرئيسيون: Halilovic, Dzeneta, Csókás, Dániel, Webster, Richard David, Stuparu, Mihaiela Corina
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Corannulene; Electron-Deficient Compounds
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/162457

Herein we show that a dibromo imide derivative of corannulene could be subjected to a palladium-catalyzed Heck reaction in order to install aryl vinylene groups in a bilateral fashion on the C5-symmetric aromatic nucleus. A photochemically-induced oxidative cyclization then affords π-extended struct...