Bilateral aromatic extension of corannulene nucleus

• Main Authors: Halilovic, Dzeneta, Csókás, Dániel, Webster, Richard David, Stuparu, Mihaiela Corina
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2022
• Subjects: Science::Chemistry; Corannulene; Electron-Deficient Compounds
• Online Access: https://hdl.handle.net/10356/162457
• Institution: Nanyang Technological University

Herein we show that a dibromo imide derivative of corannulene could be subjected to a palladium-catalyzed Heck reaction in order to install aryl vinylene groups in a bilateral fashion on the C5-symmetric aromatic nucleus. A photochemically-induced oxidative cyclization then affords π-extended struct...