Single-nitrogen atom incorporation into B=B bond via the N=N bond splitting of diazo compound and diazirine

• المؤلفون الرئيسيون: Zhu, Lizhao, Kinjo, Rei
• مؤلفون آخرون: School of Chemistry, Chemical Engineering and Biotechnology
• التنسيق: مقال
• اللغة: English
• منشور في: 2023
• الموضوعات: Science::Chemistry; B-B Unsaturated Bond; Bond Activation
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/171089

Triboraazabutenyne 3 is synthesized by the reaction of diboraazabutenyne 1 with aryl boron dibromide followed by the reduction. The ligand exchange to replace phosphine on the terminal sp2 B atom with carbene furnishes 4. 11 B NMR, solid-state structures, and computational studies disclose that 3 an...