A three-membered diazo-aluminum heterocycle to access an Al=C π bonding species

[1+2] cycloaddition between a cyclic (alkyl)(amino)aluminyl anion (3) and diaryldiazomethane affords an AlN2 three-membered ring species (4). Compound (4) is thermally unstable and spontaneously releases N2 gas under the mild reaction condition to generate an ion-separated species 5. An X-ray study...

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Bibliographic Details
Main Authors: Yan, Chenting, Kinjo, Rei
Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
Format: Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/162729
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Institution: Nanyang Technological University
Language: English