A three-membered diazo-aluminum heterocycle to access an Al=C π bonding species

• Main Authors: Yan, Chenting, Kinjo, Rei
• Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
• Format: Article
• Language: English
• Published: 2022
• Subjects: Science::Chemistry; Aluminyl Anion; Bond Cleavage
• Online Access: https://hdl.handle.net/10356/162729
• Institution: Nanyang Technological University

[1+2] cycloaddition between a cyclic (alkyl)(amino)aluminyl anion (3) and diaryldiazomethane affords an AlN2 three-membered ring species (4). Compound (4) is thermally unstable and spontaneously releases N2 gas under the mild reaction condition to generate an ion-separated species 5. An X-ray study...