Triaryl carbonium ion-pair-mediated cooperative aerobic dehydrogenation of N-heterocycles

• المؤلفون الرئيسيون: Zhang, Zhenguo, Gu, Jun, Ji, Liang, Liu, Xiaoxiao, Zhang, Ting, Lv, Yongheng, Liu, Fang, Jia, Zhenhua, Loh, Teck-Peng
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2023
• الموضوعات: Science::Chemistry; Metal Free; Ion Pair
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/171494
• المؤسسة: Nanyang Technological University

The triphenylmethyl radical was discovered by Gomberg in 1900 and has been shown to be a persistent radical species. Surprisingly, this radical is rarely used in organic synthesis since its discovery over a century ago. Here, we report a metal-free aerobic dehydrogenation of N-heterocycles mediated...