Triaryl carbonium ion-pair-mediated cooperative aerobic dehydrogenation of N-heterocycles

• Main Authors: Zhang, Zhenguo, Gu, Jun, Ji, Liang, Liu, Xiaoxiao, Zhang, Ting, Lv, Yongheng, Liu, Fang, Jia, Zhenhua, Loh, Teck-Peng
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2023
• 主題: Science::Chemistry; Metal Free; Ion Pair
• 在線閱讀: https://hdl.handle.net/10356/171494
• 機構: Nanyang Technological University

The triphenylmethyl radical was discovered by Gomberg in 1900 and has been shown to be a persistent radical species. Surprisingly, this radical is rarely used in organic synthesis since its discovery over a century ago. Here, we report a metal-free aerobic dehydrogenation of N-heterocycles mediated...